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1-[(4-Chloro-phen-yl)(phenyl-imino)-meth-yl]-7-meth-oxy-2-naphthol-1,4-diaza-bicyclo-[2.2.2]octane (2/1).

Nagasawa A, Mitsui R, Kato Y, Okamoto A, Yonezawa N - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: C-H⋯Cl inter-actions are also observed.In the triaryl-imine mol-ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings.The dihedral angle between these two latter rings is 87.09 (7)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.

ABSTRACT
In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza-bicyclo-[2.2.2]octane mol-ecule is located on a twofold rotation axis and linked to the two triaryl-imine mol-ecules by O-H⋯N hydrogen bonds, forming a 2:1 aggregate. C-H⋯Cl inter-actions are also observed. In the triaryl-imine mol-ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09 (7)°.

No MeSH data available.


The asymmetric unit of the cocrystal of triarylimine and DABCO, showing 50% probability displacement ellipsoids [symmetry code: (i) 1 - x, y, 3/2 - z].
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Fap1: The asymmetric unit of the cocrystal of triarylimine and DABCO, showing 50% probability displacement ellipsoids [symmetry code: (i) 1 - x, y, 3/2 - z].


1-[(4-Chloro-phen-yl)(phenyl-imino)-meth-yl]-7-meth-oxy-2-naphthol-1,4-diaza-bicyclo-[2.2.2]octane (2/1).

Nagasawa A, Mitsui R, Kato Y, Okamoto A, Yonezawa N - Acta Crystallogr Sect E Struct Rep Online (2010)

The asymmetric unit of the cocrystal of triarylimine and DABCO, showing 50% probability displacement ellipsoids [symmetry code: (i) 1 - x, y, 3/2 - z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983128&req=5

Fap1: The asymmetric unit of the cocrystal of triarylimine and DABCO, showing 50% probability displacement ellipsoids [symmetry code: (i) 1 - x, y, 3/2 - z].
Bottom Line: C-H⋯Cl inter-actions are also observed.In the triaryl-imine mol-ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings.The dihedral angle between these two latter rings is 87.09 (7)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.

ABSTRACT
In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza-bicyclo-[2.2.2]octane mol-ecule is located on a twofold rotation axis and linked to the two triaryl-imine mol-ecules by O-H⋯N hydrogen bonds, forming a 2:1 aggregate. C-H⋯Cl inter-actions are also observed. In the triaryl-imine mol-ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09 (7)°.

No MeSH data available.