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(S)-5-Hexyl-1-[(S)-2-hydr-oxy-1-phenyl-ethyl]-4-meth-oxy-1H-pyrrol-2(5H)-one.

Zheng JF, Jiang LJ, Guo JN - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth-oxy-3-phenyl-2,3-dihydro-pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl-silane using titanium(IV) chloride as catalyst.In the mol-ecule, the phenyl and dihydro-pyrrolone rings form a dihedral angle of 83.8 (1)°.O-H⋯O hydrogen-bonding inter-actions lead to the formation of a chain parallel to the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and the Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, People's Republic of China.

ABSTRACT
The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth-oxy-3-phenyl-2,3-dihydro-pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl-silane using titanium(IV) chloride as catalyst. In the mol-ecule, the phenyl and dihydro-pyrrolone rings form a dihedral angle of 83.8 (1)°. O-H⋯O hydrogen-bonding inter-actions lead to the formation of a chain parallel to the a axis.

No MeSH data available.


The molecular structure of the title compound with the atom-labeling scheme, showing 50% probability displacement ellipsoids. H atoms are drawn as spheres of arbitrary radius.
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Fap1: The molecular structure of the title compound with the atom-labeling scheme, showing 50% probability displacement ellipsoids. H atoms are drawn as spheres of arbitrary radius.


(S)-5-Hexyl-1-[(S)-2-hydr-oxy-1-phenyl-ethyl]-4-meth-oxy-1H-pyrrol-2(5H)-one.

Zheng JF, Jiang LJ, Guo JN - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title compound with the atom-labeling scheme, showing 50% probability displacement ellipsoids. H atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977772&req=5

Fap1: The molecular structure of the title compound with the atom-labeling scheme, showing 50% probability displacement ellipsoids. H atoms are drawn as spheres of arbitrary radius.
Bottom Line: The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth-oxy-3-phenyl-2,3-dihydro-pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl-silane using titanium(IV) chloride as catalyst.In the mol-ecule, the phenyl and dihydro-pyrrolone rings form a dihedral angle of 83.8 (1)°.O-H⋯O hydrogen-bonding inter-actions lead to the formation of a chain parallel to the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and the Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, People's Republic of China.

ABSTRACT
The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth-oxy-3-phenyl-2,3-dihydro-pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl-silane using titanium(IV) chloride as catalyst. In the mol-ecule, the phenyl and dihydro-pyrrolone rings form a dihedral angle of 83.8 (1)°. O-H⋯O hydrogen-bonding inter-actions lead to the formation of a chain parallel to the a axis.

No MeSH data available.