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5-(4-Bromo-phen-yl)-1,2,3,4-tetra-hydro-benzo[a]phenanthridine.

Xie HS, Zhang AL, Su L - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, C(23)H(18)BrN, was synthesized by the reaction of 4-bromo-benzaldehyde, naphthalen-2-amine and cyclo-hexa-none in tetra-hydro-furan, catalyzed by iodine.The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring.In the crystal, a weak C-H⋯π inter-action occurs, leading to inversion dimers.

View Article: PubMed Central - HTML - PubMed

Affiliation: Division of Science and Technology, Xuzhou Institute of Architectural Technology, Xuzhou 221116, People's Republic of China.

ABSTRACT
The title compound, C(23)H(18)BrN, was synthesized by the reaction of 4-bromo-benzaldehyde, naphthalen-2-amine and cyclo-hexa-none in tetra-hydro-furan, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C-H⋯π inter-action occurs, leading to inversion dimers.

No MeSH data available.


Related in: MedlinePlus

The molecular packing diagram showing the C—H···π stacking in the crystal of (I).
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Fap2: The molecular packing diagram showing the C—H···π stacking in the crystal of (I).


5-(4-Bromo-phen-yl)-1,2,3,4-tetra-hydro-benzo[a]phenanthridine.

Xie HS, Zhang AL, Su L - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular packing diagram showing the C—H···π stacking in the crystal of (I).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977753&req=5

Fap2: The molecular packing diagram showing the C—H···π stacking in the crystal of (I).
Bottom Line: The title compound, C(23)H(18)BrN, was synthesized by the reaction of 4-bromo-benzaldehyde, naphthalen-2-amine and cyclo-hexa-none in tetra-hydro-furan, catalyzed by iodine.The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring.In the crystal, a weak C-H⋯π inter-action occurs, leading to inversion dimers.

View Article: PubMed Central - HTML - PubMed

Affiliation: Division of Science and Technology, Xuzhou Institute of Architectural Technology, Xuzhou 221116, People's Republic of China.

ABSTRACT
The title compound, C(23)H(18)BrN, was synthesized by the reaction of 4-bromo-benzaldehyde, naphthalen-2-amine and cyclo-hexa-none in tetra-hydro-furan, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C-H⋯π inter-action occurs, leading to inversion dimers.

No MeSH data available.


Related in: MedlinePlus