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Tetra-ethyl-ammonium 12-phenyl-ethynylcarba-closo-dodeca-borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)].

Finze M, Reiss GJ - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (-) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion.The [12-PhCC-closo-CB(11)H(11)](-) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B-C C-C group, with B-C C and C C-C angles of 177.15 (16) and 176.64 (17)°, respectively.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie und Strukturchemie II, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, D-40225 Düsseldorf, Germany.

ABSTRACT
The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (-) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](-) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B-C C-C group, with B-C C and C C-C angles of 177.15 (16) and 176.64 (17)°, respectively.

No MeSH data available.


: The tetraethylammonium cation in [Et4N][12-PhCC-closo-CB11H11]. Hydrogen atoms are drawn with an arbitrary radius and the displacement ellipsoids are shown at the 40% probability level.
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Fap2: : The tetraethylammonium cation in [Et4N][12-PhCC-closo-CB11H11]. Hydrogen atoms are drawn with an arbitrary radius and the displacement ellipsoids are shown at the 40% probability level.


Tetra-ethyl-ammonium 12-phenyl-ethynylcarba-closo-dodeca-borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)].

Finze M, Reiss GJ - Acta Crystallogr Sect E Struct Rep Online (2009)

: The tetraethylammonium cation in [Et4N][12-PhCC-closo-CB11H11]. Hydrogen atoms are drawn with an arbitrary radius and the displacement ellipsoids are shown at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977730&req=5

Fap2: : The tetraethylammonium cation in [Et4N][12-PhCC-closo-CB11H11]. Hydrogen atoms are drawn with an arbitrary radius and the displacement ellipsoids are shown at the 40% probability level.
Bottom Line: The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (-) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion.The [12-PhCC-closo-CB(11)H(11)](-) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B-C C-C group, with B-C C and C C-C angles of 177.15 (16) and 176.64 (17)°, respectively.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie und Strukturchemie II, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, D-40225 Düsseldorf, Germany.

ABSTRACT
The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (-) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](-) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B-C C-C group, with B-C C and C C-C angles of 177.15 (16) and 176.64 (17)°, respectively.

No MeSH data available.