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(1-Adamant-yl)(4-amino-phen-yl)methanol.

Rouchal M, Nečas M, Vícha R - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The mol-ecules adopt slightly different conformations and contain an adamantane cage consisting of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles varying within the range 107.2 (4)-111.4 (4)°.In the hydrogen-bonded pair, the benzene rings are almost coplanar, the dihedral angle between them being 1.29 (13)°.The mol-ecular packing in the crystal is stabilized by additional inter-molecular N-H⋯O hydrogen bonds.

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ABSTRACT
In the racemic crystal of the title compound, C(17)H(23)NO, enanti-omers of the two crystallographically independent mol-ecules are linked into face-to-face RSdimers via inter-molecular O-H⋯N hydrogen bonds and π-π inter-actions with centroid-centroid distances of 3.7610 (2) Å. The mol-ecules adopt slightly different conformations and contain an adamantane cage consisting of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles varying within the range 107.2 (4)-111.4 (4)°. In the hydrogen-bonded pair, the benzene rings are almost coplanar, the dihedral angle between them being 1.29 (13)°. The mol-ecular packing in the crystal is stabilized by additional inter-molecular N-H⋯O hydrogen bonds.

No MeSH data available.


The hydrogen bond cross-linkage in the three-dimensional framework, viewed along the c axis, is drawn by dotted lines. Hydrogen atoms have been omitted for enhanced clarity.
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Fap2: The hydrogen bond cross-linkage in the three-dimensional framework, viewed along the c axis, is drawn by dotted lines. Hydrogen atoms have been omitted for enhanced clarity.


(1-Adamant-yl)(4-amino-phen-yl)methanol.

Rouchal M, Nečas M, Vícha R - Acta Crystallogr Sect E Struct Rep Online (2009)

The hydrogen bond cross-linkage in the three-dimensional framework, viewed along the c axis, is drawn by dotted lines. Hydrogen atoms have been omitted for enhanced clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977704&req=5

Fap2: The hydrogen bond cross-linkage in the three-dimensional framework, viewed along the c axis, is drawn by dotted lines. Hydrogen atoms have been omitted for enhanced clarity.
Bottom Line: The mol-ecules adopt slightly different conformations and contain an adamantane cage consisting of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles varying within the range 107.2 (4)-111.4 (4)°.In the hydrogen-bonded pair, the benzene rings are almost coplanar, the dihedral angle between them being 1.29 (13)°.The mol-ecular packing in the crystal is stabilized by additional inter-molecular N-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the racemic crystal of the title compound, C(17)H(23)NO, enanti-omers of the two crystallographically independent mol-ecules are linked into face-to-face RSdimers via inter-molecular O-H⋯N hydrogen bonds and π-π inter-actions with centroid-centroid distances of 3.7610 (2) Å. The mol-ecules adopt slightly different conformations and contain an adamantane cage consisting of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles varying within the range 107.2 (4)-111.4 (4)°. In the hydrogen-bonded pair, the benzene rings are almost coplanar, the dihedral angle between them being 1.29 (13)°. The mol-ecular packing in the crystal is stabilized by additional inter-molecular N-H⋯O hydrogen bonds.

No MeSH data available.