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2-(Methoxy-carbon-yl)anilinium dihydrogen phosphate.

Shafiq M, Khan IU, Arshad MN, Khan MH, Simpson J - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°.In the crystal, adjacent cations and anions form dimers through N-H⋯O and O-H⋯O hydrogen bonds, respectively.Additional N-H⋯O and C-H⋯O contacts result in a network of cation and anion dimers stacked down the b axis.

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ABSTRACT
The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (-), is a derivative of the naturally occurring compound methyl-anthranilate. The asymmetric unit comprises the 2-(methoxy-carbon-yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°. In the crystal, adjacent cations and anions form dimers through N-H⋯O and O-H⋯O hydrogen bonds, respectively. Additional N-H⋯O and C-H⋯O contacts result in a network of cation and anion dimers stacked down the b axis.

No MeSH data available.


The asymmetric unit of (I) with displacement ellipsoids for the non-hydrogen atoms drawn at the 50% probability level. Hydrogen bonds are drawn as dashed lines.
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Fap1: The asymmetric unit of (I) with displacement ellipsoids for the non-hydrogen atoms drawn at the 50% probability level. Hydrogen bonds are drawn as dashed lines.


2-(Methoxy-carbon-yl)anilinium dihydrogen phosphate.

Shafiq M, Khan IU, Arshad MN, Khan MH, Simpson J - Acta Crystallogr Sect E Struct Rep Online (2009)

The asymmetric unit of (I) with displacement ellipsoids for the non-hydrogen atoms drawn at the 50% probability level. Hydrogen bonds are drawn as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977506&req=5

Fap1: The asymmetric unit of (I) with displacement ellipsoids for the non-hydrogen atoms drawn at the 50% probability level. Hydrogen bonds are drawn as dashed lines.
Bottom Line: In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°.In the crystal, adjacent cations and anions form dimers through N-H⋯O and O-H⋯O hydrogen bonds, respectively.Additional N-H⋯O and C-H⋯O contacts result in a network of cation and anion dimers stacked down the b axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (-), is a derivative of the naturally occurring compound methyl-anthranilate. The asymmetric unit comprises the 2-(methoxy-carbon-yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°. In the crystal, adjacent cations and anions form dimers through N-H⋯O and O-H⋯O hydrogen bonds, respectively. Additional N-H⋯O and C-H⋯O contacts result in a network of cation and anion dimers stacked down the b axis.

No MeSH data available.