Limits...
5-Iodo-2-phenyl-3-phenyl-sulfinyl-1-benzofuran.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, C(20)H(13)IO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [83.84 (5)°].The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 40.47 (5)°.The crystal structure is stabilized by non-classical inter-molecular C-H⋯O inter-actions, and by an I⋯O halogen bond of 3.124 (1) Å [C-I⋯O = 165.84 (5)°].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(20)H(13)IO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [83.84 (5)°]. The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 40.47 (5)°. The crystal structure is stabilized by non-classical inter-molecular C-H⋯O inter-actions, and by an I⋯O halogen bond of 3.124 (1) Å [C-I⋯O = 165.84 (5)°].

No MeSH data available.


The C–H···O hydrogen bond and I···O halogen bond (dotted lines) in the title compound. [Symmetry code: (i) -x, -y, -z; (ii) x, y, z + 1; (iii) -x, -y, -z + 1; (iv) -x, -y + 1, -z + 1; (v) x, y, z - 1.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2977478&req=5

Fap2: The C–H···O hydrogen bond and I···O halogen bond (dotted lines) in the title compound. [Symmetry code: (i) -x, -y, -z; (ii) x, y, z + 1; (iii) -x, -y, -z + 1; (iv) -x, -y + 1, -z + 1; (v) x, y, z - 1.]


5-Iodo-2-phenyl-3-phenyl-sulfinyl-1-benzofuran.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2009)

The C–H···O hydrogen bond and I···O halogen bond (dotted lines) in the title compound. [Symmetry code: (i) -x, -y, -z; (ii) x, y, z + 1; (iii) -x, -y, -z + 1; (iv) -x, -y + 1, -z + 1; (v) x, y, z - 1.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977478&req=5

Fap2: The C–H···O hydrogen bond and I···O halogen bond (dotted lines) in the title compound. [Symmetry code: (i) -x, -y, -z; (ii) x, y, z + 1; (iii) -x, -y, -z + 1; (iv) -x, -y + 1, -z + 1; (v) x, y, z - 1.]
Bottom Line: In the title compound, C(20)H(13)IO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [83.84 (5)°].The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 40.47 (5)°.The crystal structure is stabilized by non-classical inter-molecular C-H⋯O inter-actions, and by an I⋯O halogen bond of 3.124 (1) Å [C-I⋯O = 165.84 (5)°].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(20)H(13)IO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [83.84 (5)°]. The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 40.47 (5)°. The crystal structure is stabilized by non-classical inter-molecular C-H⋯O inter-actions, and by an I⋯O halogen bond of 3.124 (1) Å [C-I⋯O = 165.84 (5)°].

No MeSH data available.