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1(2,3),2(3,2),3(2,3),4(3,2)-Tetra-kis(1-benzothio-phena)cyclo-tetra-phane benzene sesquisolvate.

Wang ZH, Shi JW, Zhu S, Wang H - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclo-octa-tetra-ene (COT) ring compound has approximate local D(2) point symmetry of the so-called 'saddle' form: the dihedral angles between neighboring benzo[b]thio-phene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°.The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring mol-ecule may indicate S⋯π inter-actions in the crystal.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory for Special Functional Materials of the Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China.

ABSTRACT
In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclo-octa-tetra-ene (COT) ring compound has approximate local D(2) point symmetry of the so-called 'saddle' form: the dihedral angles between neighboring benzo[b]thio-phene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°. The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring mol-ecule may indicate S⋯π inter-actions in the crystal.

No MeSH data available.


The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level.
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Fap1: The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level.


1(2,3),2(3,2),3(2,3),4(3,2)-Tetra-kis(1-benzothio-phena)cyclo-tetra-phane benzene sesquisolvate.

Wang ZH, Shi JW, Zhu S, Wang H - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977466&req=5

Fap1: The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclo-octa-tetra-ene (COT) ring compound has approximate local D(2) point symmetry of the so-called 'saddle' form: the dihedral angles between neighboring benzo[b]thio-phene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°.The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring mol-ecule may indicate S⋯π inter-actions in the crystal.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory for Special Functional Materials of the Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China.

ABSTRACT
In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclo-octa-tetra-ene (COT) ring compound has approximate local D(2) point symmetry of the so-called 'saddle' form: the dihedral angles between neighboring benzo[b]thio-phene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°. The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring mol-ecule may indicate S⋯π inter-actions in the crystal.

No MeSH data available.