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Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolato-κN,O}copper(II).

Dong WK, Tong JF, An LL, Wu JC, Yao J - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands.In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment.The inter-planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

ABSTRACT
In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter-planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance.

No MeSH data available.


The molecular structure of the title complex with atom numbering scheme. Displacement ellipsoids for non-hydrogen atoms are drawn at the 30% probability level.
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Fap1: The molecular structure of the title complex with atom numbering scheme. Displacement ellipsoids for non-hydrogen atoms are drawn at the 30% probability level.


Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolato-κN,O}copper(II).

Dong WK, Tong JF, An LL, Wu JC, Yao J - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title complex with atom numbering scheme. Displacement ellipsoids for non-hydrogen atoms are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977463&req=5

Fap1: The molecular structure of the title complex with atom numbering scheme. Displacement ellipsoids for non-hydrogen atoms are drawn at the 30% probability level.
Bottom Line: In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands.In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment.The inter-planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

ABSTRACT
In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter-planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance.

No MeSH data available.