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Di-μ-perchlorato-bis-{μ-2-[(2-pyrid-yl)methyl-amino-meth-yl]phenolato)dicopper(II) acetonitrile disolvate.

Assey GE, Yisgedu T, Gultneh Y, Butcher RJ, Tesema Y - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The asymmetric unit contains two acetonitrile solvent mol-ecules.In the crystal structure, in addition to N-H⋯O hydrogen bonds, there are weak C-H⋯O inter-actions between the perchlorate O atoms and the reduced Schiff base ligand.C-H⋯N inter-actions are also present.

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Affiliation: Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.

ABSTRACT
In the crystal of the dinuclear title compound, [Cu(2)(C(13)H(13)N(2)O)(2)(ClO(4))(2)]·2CH(3)CN, the two bridging perchlorate ions chelate to the two Cu(II) atoms in a μ-O:O' fashion on opposite sides of the equatorial plane. The Cu(II) ions display a distorted octa-hedral coordination geometry (in the usual 4 + 2 Jahn-Teller arrangement), each being coordinated by two O atoms from the two perchlorate ligands, and two N and O atoms from the reduced Schiff base ligand. The asymmetric unit contains two acetonitrile solvent mol-ecules. In the crystal structure, in addition to N-H⋯O hydrogen bonds, there are weak C-H⋯O inter-actions between the perchlorate O atoms and the reduced Schiff base ligand. C-H⋯N inter-actions are also present.

No MeSH data available.


The molecular structure of the dinuclear complex, C26H26Cl2Cu2N4O10 showing the atom numbering scheme and 50% probability displacement ellipsoids.
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Fap1: The molecular structure of the dinuclear complex, C26H26Cl2Cu2N4O10 showing the atom numbering scheme and 50% probability displacement ellipsoids.


Di-μ-perchlorato-bis-{μ-2-[(2-pyrid-yl)methyl-amino-meth-yl]phenolato)dicopper(II) acetonitrile disolvate.

Assey GE, Yisgedu T, Gultneh Y, Butcher RJ, Tesema Y - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the dinuclear complex, C26H26Cl2Cu2N4O10 showing the atom numbering scheme and 50% probability displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977449&req=5

Fap1: The molecular structure of the dinuclear complex, C26H26Cl2Cu2N4O10 showing the atom numbering scheme and 50% probability displacement ellipsoids.
Bottom Line: The asymmetric unit contains two acetonitrile solvent mol-ecules.In the crystal structure, in addition to N-H⋯O hydrogen bonds, there are weak C-H⋯O inter-actions between the perchlorate O atoms and the reduced Schiff base ligand.C-H⋯N inter-actions are also present.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.

ABSTRACT
In the crystal of the dinuclear title compound, [Cu(2)(C(13)H(13)N(2)O)(2)(ClO(4))(2)]·2CH(3)CN, the two bridging perchlorate ions chelate to the two Cu(II) atoms in a μ-O:O' fashion on opposite sides of the equatorial plane. The Cu(II) ions display a distorted octa-hedral coordination geometry (in the usual 4 + 2 Jahn-Teller arrangement), each being coordinated by two O atoms from the two perchlorate ligands, and two N and O atoms from the reduced Schiff base ligand. The asymmetric unit contains two acetonitrile solvent mol-ecules. In the crystal structure, in addition to N-H⋯O hydrogen bonds, there are weak C-H⋯O inter-actions between the perchlorate O atoms and the reduced Schiff base ligand. C-H⋯N inter-actions are also present.

No MeSH data available.