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catena-Poly[[diaqua-nickel(II)]-bis-(μ-pyridine-4-sulfinato)-κN,O;κO,N].

Du ZX, Ji SN - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title coordination polymer, [Ni(C(5)H(4)NO(2)S)(2)(H(2)O)(2)](n), the Ni(II) ion is located on an inversion centre and is octa-hedrally coordinated by two N and two O atoms of four symmetry-related and deprotonated pyridine-4-sulfinate (ps) ligands together with two water mol-ecules in axial positions.The ps(-) anions, acting as μ(2)-bridging ligands, link neighbouring Ni(II) ions into a chain structure along the c axis.These polymeric chains are extended into a three-dimensional framework via inter-molecular O-H⋯O hydrogen bonds with participation of the water mol-ecules.

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Affiliation: Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, People's Republic of China.

ABSTRACT
In the title coordination polymer, [Ni(C(5)H(4)NO(2)S)(2)(H(2)O)(2)](n), the Ni(II) ion is located on an inversion centre and is octa-hedrally coordinated by two N and two O atoms of four symmetry-related and deprotonated pyridine-4-sulfinate (ps) ligands together with two water mol-ecules in axial positions. The ps(-) anions, acting as μ(2)-bridging ligands, link neighbouring Ni(II) ions into a chain structure along the c axis. These polymeric chains are extended into a three-dimensional framework via inter-molecular O-H⋯O hydrogen bonds with participation of the water mol-ecules.

No MeSH data available.


Related in: MedlinePlus

Packing diagram for (1), showing hydrogen bonds as dashed lines in ab plane. H atoms on C have been deleted.
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Fap3: Packing diagram for (1), showing hydrogen bonds as dashed lines in ab plane. H atoms on C have been deleted.


catena-Poly[[diaqua-nickel(II)]-bis-(μ-pyridine-4-sulfinato)-κN,O;κO,N].

Du ZX, Ji SN - Acta Crystallogr Sect E Struct Rep Online (2009)

Packing diagram for (1), showing hydrogen bonds as dashed lines in ab plane. H atoms on C have been deleted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977425&req=5

Fap3: Packing diagram for (1), showing hydrogen bonds as dashed lines in ab plane. H atoms on C have been deleted.
Bottom Line: In the title coordination polymer, [Ni(C(5)H(4)NO(2)S)(2)(H(2)O)(2)](n), the Ni(II) ion is located on an inversion centre and is octa-hedrally coordinated by two N and two O atoms of four symmetry-related and deprotonated pyridine-4-sulfinate (ps) ligands together with two water mol-ecules in axial positions.The ps(-) anions, acting as μ(2)-bridging ligands, link neighbouring Ni(II) ions into a chain structure along the c axis.These polymeric chains are extended into a three-dimensional framework via inter-molecular O-H⋯O hydrogen bonds with participation of the water mol-ecules.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, People's Republic of China.

ABSTRACT
In the title coordination polymer, [Ni(C(5)H(4)NO(2)S)(2)(H(2)O)(2)](n), the Ni(II) ion is located on an inversion centre and is octa-hedrally coordinated by two N and two O atoms of four symmetry-related and deprotonated pyridine-4-sulfinate (ps) ligands together with two water mol-ecules in axial positions. The ps(-) anions, acting as μ(2)-bridging ligands, link neighbouring Ni(II) ions into a chain structure along the c axis. These polymeric chains are extended into a three-dimensional framework via inter-molecular O-H⋯O hydrogen bonds with participation of the water mol-ecules.

No MeSH data available.


Related in: MedlinePlus