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A new coordination tetra-mer of copper(I) iodide and benzyl-dimethyl-amine: tetra-μ(3)-iodido-tetra-kis[(benzyl-dimethyl-amine-κN)copper(I)].

Yang S, Li Y, Cui Y, Pan J - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand.Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms.The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) Å.

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Affiliation: State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

ABSTRACT
The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) Å.

No MeSH data available.


The symmetric unit structure of Cu4I4(C9H13N)4 with displacement ellipsoids drawn at the 45% probability level.
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Fap1: The symmetric unit structure of Cu4I4(C9H13N)4 with displacement ellipsoids drawn at the 45% probability level.


A new coordination tetra-mer of copper(I) iodide and benzyl-dimethyl-amine: tetra-μ(3)-iodido-tetra-kis[(benzyl-dimethyl-amine-κN)copper(I)].

Yang S, Li Y, Cui Y, Pan J - Acta Crystallogr Sect E Struct Rep Online (2009)

The symmetric unit structure of Cu4I4(C9H13N)4 with displacement ellipsoids drawn at the 45% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977424&req=5

Fap1: The symmetric unit structure of Cu4I4(C9H13N)4 with displacement ellipsoids drawn at the 45% probability level.
Bottom Line: Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand.Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms.The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

ABSTRACT
The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) Å.

No MeSH data available.