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1,15:21,35-Bis(oxydiethyl-ene)-5,8,11,18,25,28,31,38-octa-oxa-1,15,21,35-tetra-azacyclo-tetra-decane-16,20,36,40-tetra-one-benzene (1/2): a macrotricyclic tetra-lactam.

Smith GL, Nguyen T, Powell DR, Taylor RW - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry.The mol-ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza-tetra-oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl-ene bridges.The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry. The mol-ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza-tetra-oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl-ene bridges. The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity.

No MeSH data available.


The molecular structure of (I), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. Unlabelled atoms are related to their labelled counterparts by (1-x, 1-y, 1-z).
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Fap1: The molecular structure of (I), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. Unlabelled atoms are related to their labelled counterparts by (1-x, 1-y, 1-z).


1,15:21,35-Bis(oxydiethyl-ene)-5,8,11,18,25,28,31,38-octa-oxa-1,15,21,35-tetra-azacyclo-tetra-decane-16,20,36,40-tetra-one-benzene (1/2): a macrotricyclic tetra-lactam.

Smith GL, Nguyen T, Powell DR, Taylor RW - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of (I), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. Unlabelled atoms are related to their labelled counterparts by (1-x, 1-y, 1-z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977422&req=5

Fap1: The molecular structure of (I), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. Unlabelled atoms are related to their labelled counterparts by (1-x, 1-y, 1-z).
Bottom Line: The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry.The mol-ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza-tetra-oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl-ene bridges.The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry. The mol-ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza-tetra-oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl-ene bridges. The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity.

No MeSH data available.