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trans-Dibromidobis(triphenyl-phosphine-κP)palladium(II) chloro-form monosolvate.

Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement.The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.

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Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement. The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.

No MeSH data available.


Molecular structure of the title compound. Displacement ellipsoids are drawn at the 70% probability level.
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Fap1: Molecular structure of the title compound. Displacement ellipsoids are drawn at the 70% probability level.


trans-Dibromidobis(triphenyl-phosphine-κP)palladium(II) chloro-form monosolvate.

Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2009)

Molecular structure of the title compound. Displacement ellipsoids are drawn at the 70% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977421&req=5

Fap1: Molecular structure of the title compound. Displacement ellipsoids are drawn at the 70% probability level.
Bottom Line: The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement.The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement. The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.

No MeSH data available.