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Nonapiperidinium monohydrogen deca-vanadate tetra-nitrate.

Graia M, Ksiksi R, Driss A - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca-vanadate polyanion which lies on an inversion center.All the piperidinium cations adopt chair conformations.In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form chains along [001].

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Affiliation: Laboratoire de Matériaux et de Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis-El Manar, 2092 El Manar II Tunis, Tunisia.

ABSTRACT
The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca-vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center.

No MeSH data available.


Related in: MedlinePlus

View of the decavanadate unit of the title compound. Thermal ellipsoids are drawn at 35% probability. The purple spheres are vanadium atoms and the red spheres are oxygen atoms.
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Fap1: View of the decavanadate unit of the title compound. Thermal ellipsoids are drawn at 35% probability. The purple spheres are vanadium atoms and the red spheres are oxygen atoms.


Nonapiperidinium monohydrogen deca-vanadate tetra-nitrate.

Graia M, Ksiksi R, Driss A - Acta Crystallogr Sect E Struct Rep Online (2009)

View of the decavanadate unit of the title compound. Thermal ellipsoids are drawn at 35% probability. The purple spheres are vanadium atoms and the red spheres are oxygen atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977420&req=5

Fap1: View of the decavanadate unit of the title compound. Thermal ellipsoids are drawn at 35% probability. The purple spheres are vanadium atoms and the red spheres are oxygen atoms.
Bottom Line: The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca-vanadate polyanion which lies on an inversion center.All the piperidinium cations adopt chair conformations.In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form chains along [001].

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Matériaux et de Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis-El Manar, 2092 El Manar II Tunis, Tunisia.

ABSTRACT
The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca-vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center.

No MeSH data available.


Related in: MedlinePlus