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4,4'-Di-tert-butyl-2,2'-bipyridine.

Amarante TR, Figueiredo S, Lopes AD, Gonçalves IS, Almeida Paz FA - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, C(18)H(24)N(2), the mol-ecular unit adopts a trans conformation around the central C-C bond [N-C-C-N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°].The crystal packing is driven by co-operative contacts involving weak C-H⋯N and C-H⋯π inter-actions, and also the need to fill effectively the available space.

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ABSTRACT
In the title compound, C(18)H(24)N(2), the mol-ecular unit adopts a trans conformation around the central C-C bond [N-C-C-N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°]. The crystal packing is driven by co-operative contacts involving weak C-H⋯N and C-H⋯π inter-actions, and also the need to fill effectively the available space.

No MeSH data available.


Related in: MedlinePlus

Asymmetric unit of the title compound with all non-hydrogen atoms represented as thermal ellipsoids drawn at the 50% probability level.
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Fap3: Asymmetric unit of the title compound with all non-hydrogen atoms represented as thermal ellipsoids drawn at the 50% probability level.


4,4'-Di-tert-butyl-2,2'-bipyridine.

Amarante TR, Figueiredo S, Lopes AD, Gonçalves IS, Almeida Paz FA - Acta Crystallogr Sect E Struct Rep Online (2009)

Asymmetric unit of the title compound with all non-hydrogen atoms represented as thermal ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977408&req=5

Fap3: Asymmetric unit of the title compound with all non-hydrogen atoms represented as thermal ellipsoids drawn at the 50% probability level.
Bottom Line: In the title compound, C(18)H(24)N(2), the mol-ecular unit adopts a trans conformation around the central C-C bond [N-C-C-N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°].The crystal packing is driven by co-operative contacts involving weak C-H⋯N and C-H⋯π inter-actions, and also the need to fill effectively the available space.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(18)H(24)N(2), the mol-ecular unit adopts a trans conformation around the central C-C bond [N-C-C-N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°]. The crystal packing is driven by co-operative contacts involving weak C-H⋯N and C-H⋯π inter-actions, and also the need to fill effectively the available space.

No MeSH data available.


Related in: MedlinePlus