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1,4-Diazo-niabicyclo-[2.2.2]octane diaqua-dichlorido-(oxalato-κO,O')iron(III) chloride.

Cai Y - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes.The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry.Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.

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Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.

No MeSH data available.


The crystal packing viewed along the a axis. Hydrogen atoms not involved in hydrogen bonding (dashed lines) were omitted for clarity.
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Fap2: The crystal packing viewed along the a axis. Hydrogen atoms not involved in hydrogen bonding (dashed lines) were omitted for clarity.


1,4-Diazo-niabicyclo-[2.2.2]octane diaqua-dichlorido-(oxalato-κO,O')iron(III) chloride.

Cai Y - Acta Crystallogr Sect E Struct Rep Online (2009)

The crystal packing viewed along the a axis. Hydrogen atoms not involved in hydrogen bonding (dashed lines) were omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977407&req=5

Fap2: The crystal packing viewed along the a axis. Hydrogen atoms not involved in hydrogen bonding (dashed lines) were omitted for clarity.
Bottom Line: In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes.The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry.Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.

No MeSH data available.