Limits...
2-(4-Bromo-phen-yl)-1-(phenyl-sulfin-yl)naphtho[2,1-b]furan.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the crystal structure, non-classical inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds are observed.The crystal structure also exhibits aromatic π-π inter-actions between the furan ring and the central benzene ring of the adjacent naphthofuran system [centroid-centroid distance = 3.768 (3) Å].In addition, inter-molecular C-Br⋯π inter-actions [3.866 (2) Å] between the Br atom and the phenyl ring of the phenyl-sulfinyl substituent are present.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(24)H(15)BrO(2)S, the sulfinyl O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane through the naphthofuran fragment. The phenyl ring is nearly perpendicular to the plane of the tricyclic naphthofuran system [81.77 (6)°] and is tilted slightly towards it. The 4-bromo-phenyl ring is rotated out of the naphthofuran plane by a dihedral angle of 31.12 (4)°. In the crystal structure, non-classical inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds are observed. The crystal structure also exhibits aromatic π-π inter-actions between the furan ring and the central benzene ring of the adjacent naphthofuran system [centroid-centroid distance = 3.768 (3) Å]. In addition, inter-molecular C-Br⋯π inter-actions [3.866 (2) Å] between the Br atom and the phenyl ring of the phenyl-sulfinyl substituent are present.

No MeSH data available.


The C–H···O and C–H···Br interactions (dotted lines) in the title compound. [Symmetry code: (i) x - 1, y, z; (ii) - x + 2, - y + 1, - z + 1; (iii) x + 1, y, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2977400&req=5

Fap2: The C–H···O and C–H···Br interactions (dotted lines) in the title compound. [Symmetry code: (i) x - 1, y, z; (ii) - x + 2, - y + 1, - z + 1; (iii) x + 1, y, z.]


2-(4-Bromo-phen-yl)-1-(phenyl-sulfin-yl)naphtho[2,1-b]furan.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2009)

The C–H···O and C–H···Br interactions (dotted lines) in the title compound. [Symmetry code: (i) x - 1, y, z; (ii) - x + 2, - y + 1, - z + 1; (iii) x + 1, y, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977400&req=5

Fap2: The C–H···O and C–H···Br interactions (dotted lines) in the title compound. [Symmetry code: (i) x - 1, y, z; (ii) - x + 2, - y + 1, - z + 1; (iii) x + 1, y, z.]
Bottom Line: In the crystal structure, non-classical inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds are observed.The crystal structure also exhibits aromatic π-π inter-actions between the furan ring and the central benzene ring of the adjacent naphthofuran system [centroid-centroid distance = 3.768 (3) Å].In addition, inter-molecular C-Br⋯π inter-actions [3.866 (2) Å] between the Br atom and the phenyl ring of the phenyl-sulfinyl substituent are present.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(24)H(15)BrO(2)S, the sulfinyl O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane through the naphthofuran fragment. The phenyl ring is nearly perpendicular to the plane of the tricyclic naphthofuran system [81.77 (6)°] and is tilted slightly towards it. The 4-bromo-phenyl ring is rotated out of the naphthofuran plane by a dihedral angle of 31.12 (4)°. In the crystal structure, non-classical inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds are observed. The crystal structure also exhibits aromatic π-π inter-actions between the furan ring and the central benzene ring of the adjacent naphthofuran system [centroid-centroid distance = 3.768 (3) Å]. In addition, inter-molecular C-Br⋯π inter-actions [3.866 (2) Å] between the Br atom and the phenyl ring of the phenyl-sulfinyl substituent are present.

No MeSH data available.