Limits...
Hexaaqua-cobalt(II) 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate).

Liang WL, Yu Q, Zhang XQ, Qin JK, Liang H - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate) (battp(2-)) anion.The Co(II) center is coordinated by six H(2)O mol-ecules in a distorted octa-hedral coordination environment.In the crystal structure, intra- and inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π-π contacts between the tetra-zole rings [centroid-centroid distance = 3.346 (1) Å] may further stabilize the structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China.

ABSTRACT
The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate) (battp(2-)) anion. The Co(II) center is coordinated by six H(2)O mol-ecules in a distorted octa-hedral coordination environment. In the crystal structure, intra- and inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π-π contacts between the tetra-zole rings [centroid-centroid distance = 3.346 (1) Å] may further stabilize the structure.

No MeSH data available.


A partial packing diagram. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2977396&req=5

Fap2: A partial packing diagram. Hydrogen bonds are shown as dashed lines.


Hexaaqua-cobalt(II) 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate).

Liang WL, Yu Q, Zhang XQ, Qin JK, Liang H - Acta Crystallogr Sect E Struct Rep Online (2009)

A partial packing diagram. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977396&req=5

Fap2: A partial packing diagram. Hydrogen bonds are shown as dashed lines.
Bottom Line: The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate) (battp(2-)) anion.The Co(II) center is coordinated by six H(2)O mol-ecules in a distorted octa-hedral coordination environment.In the crystal structure, intra- and inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π-π contacts between the tetra-zole rings [centroid-centroid distance = 3.346 (1) Å] may further stabilize the structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China.

ABSTRACT
The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate) (battp(2-)) anion. The Co(II) center is coordinated by six H(2)O mol-ecules in a distorted octa-hedral coordination environment. In the crystal structure, intra- and inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π-π contacts between the tetra-zole rings [centroid-centroid distance = 3.346 (1) Å] may further stabilize the structure.

No MeSH data available.