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Di-μ-benzoato-κO,O':O;κO:O,O'-bis-[(acetato-κO)(1,10-phenanthroline-κN,N')lead(II)] dihydrate.

Gao J, Xuan X - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol-ecules.Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms.The crystal packing is stabilized by O-H⋯O hydrogen bonds and by π-π inter-actions between the phen rings of neighboring mol-ecules, with a centroid-centroid distance of 3.577 (3) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Henan Normal University, Xinxiang 453007, People's Republic of China.

ABSTRACT
The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol-ecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by π-π inter-actions between the phen rings of neighboring mol-ecules, with a centroid-centroid distance of 3.577 (3) Å.

No MeSH data available.


Part of the crystal structure of (I), showing the hydrogen-bonding (dashed lines) interactions.
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Fap2: Part of the crystal structure of (I), showing the hydrogen-bonding (dashed lines) interactions.


Di-μ-benzoato-κO,O':O;κO:O,O'-bis-[(acetato-κO)(1,10-phenanthroline-κN,N')lead(II)] dihydrate.

Gao J, Xuan X - Acta Crystallogr Sect E Struct Rep Online (2009)

Part of the crystal structure of (I), showing the hydrogen-bonding (dashed lines) interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977393&req=5

Fap2: Part of the crystal structure of (I), showing the hydrogen-bonding (dashed lines) interactions.
Bottom Line: The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol-ecules.Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms.The crystal packing is stabilized by O-H⋯O hydrogen bonds and by π-π inter-actions between the phen rings of neighboring mol-ecules, with a centroid-centroid distance of 3.577 (3) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Henan Normal University, Xinxiang 453007, People's Republic of China.

ABSTRACT
The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol-ecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by π-π inter-actions between the phen rings of neighboring mol-ecules, with a centroid-centroid distance of 3.577 (3) Å.

No MeSH data available.