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{2,2'-[o-Phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}dipyridinecobalt(III) perchlorate.

Salehi M, Meghdadi S, Amirnasr M, Mereiter K - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: There are two pyridine mol-ecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°].The Co complexes are stacked in layers parallel to (100).Coherence of the structure is provided by a variety of C-H⋯O interactions between the complexes and the perchlor-ate counter anion.

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ABSTRACT
The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine mol-ecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C-H⋯O interactions between the complexes and the perchlor-ate counter anion.

No MeSH data available.


The ORTEP drawing of (I), with the atom labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: The ORTEP drawing of (I), with the atom labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.


{2,2'-[o-Phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}dipyridinecobalt(III) perchlorate.

Salehi M, Meghdadi S, Amirnasr M, Mereiter K - Acta Crystallogr Sect E Struct Rep Online (2009)

The ORTEP drawing of (I), with the atom labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977385&req=5

Fap1: The ORTEP drawing of (I), with the atom labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: There are two pyridine mol-ecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°].The Co complexes are stacked in layers parallel to (100).Coherence of the structure is provided by a variety of C-H⋯O interactions between the complexes and the perchlor-ate counter anion.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine mol-ecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C-H⋯O interactions between the complexes and the perchlor-ate counter anion.

No MeSH data available.