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Bis[1,3-bis-(benzimidazol-2-yl)-2-oxa-propane]cobalt(II) dipicrate acetonitrile tris-olvate.

Wu H, Yun R, Huang X, Sun Q, Qi B - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles.The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds.One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

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ABSTRACT
In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds. One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

No MeSH data available.


Part of the crystal structure with hydrogen bonds shown as dashed lines.
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Fap2: Part of the crystal structure with hydrogen bonds shown as dashed lines.


Bis[1,3-bis-(benzimidazol-2-yl)-2-oxa-propane]cobalt(II) dipicrate acetonitrile tris-olvate.

Wu H, Yun R, Huang X, Sun Q, Qi B - Acta Crystallogr Sect E Struct Rep Online (2009)

Part of the crystal structure with hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977374&req=5

Fap2: Part of the crystal structure with hydrogen bonds shown as dashed lines.
Bottom Line: In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles.The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds.One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds. One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

No MeSH data available.