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Bis[1,3-bis-(benzimidazol-2-yl)-2-oxa-propane]cobalt(II) dipicrate acetonitrile tris-olvate.

Wu H, Yun R, Huang X, Sun Q, Qi B - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles.The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds.One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds. One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

No MeSH data available.


Molecular structure and atom numbering for the cation of the title compound. Hydrogen atoms have been omitted for clarity and the displacement ellipsoids are shown at the 30% probability level [symmetry code: (A) -x+1, y, -z+3/2].
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Fap1: Molecular structure and atom numbering for the cation of the title compound. Hydrogen atoms have been omitted for clarity and the displacement ellipsoids are shown at the 30% probability level [symmetry code: (A) -x+1, y, -z+3/2].


Bis[1,3-bis-(benzimidazol-2-yl)-2-oxa-propane]cobalt(II) dipicrate acetonitrile tris-olvate.

Wu H, Yun R, Huang X, Sun Q, Qi B - Acta Crystallogr Sect E Struct Rep Online (2009)

Molecular structure and atom numbering for the cation of the title compound. Hydrogen atoms have been omitted for clarity and the displacement ellipsoids are shown at the 30% probability level [symmetry code: (A) -x+1, y, -z+3/2].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977374&req=5

Fap1: Molecular structure and atom numbering for the cation of the title compound. Hydrogen atoms have been omitted for clarity and the displacement ellipsoids are shown at the 30% probability level [symmetry code: (A) -x+1, y, -z+3/2].
Bottom Line: In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles.The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds.One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds. One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

No MeSH data available.