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catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-κN)pyrazine]cadmium(II)]-di-μ-thio-cyanato-κS:N;κN:S].

Li H, Xie LM - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis.The Cd(II) centre assumes a distorted octa-hedral geometry.The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].

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ABSTRACT
The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa-hedral geometry. The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].

No MeSH data available.


Coordination around the Cd atom with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y, -z + 1 (ii) -x + 1, y, -z + 3/2 (iii) x, -y, z + 1/2 (iv) -x + 1, -y, -z + 2]
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Fap1: Coordination around the Cd atom with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y, -z + 1 (ii) -x + 1, y, -z + 3/2 (iii) x, -y, z + 1/2 (iv) -x + 1, -y, -z + 2]


catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-κN)pyrazine]cadmium(II)]-di-μ-thio-cyanato-κS:N;κN:S].

Li H, Xie LM - Acta Crystallogr Sect E Struct Rep Online (2009)

Coordination around the Cd atom with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y, -z + 1 (ii) -x + 1, y, -z + 3/2 (iii) x, -y, z + 1/2 (iv) -x + 1, -y, -z + 2]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977348&req=5

Fap1: Coordination around the Cd atom with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y, -z + 1 (ii) -x + 1, y, -z + 3/2 (iii) x, -y, z + 1/2 (iv) -x + 1, -y, -z + 2]
Bottom Line: The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis.The Cd(II) centre assumes a distorted octa-hedral geometry.The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa-hedral geometry. The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].

No MeSH data available.