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Bis(1,10-phenanthroline-κN,N')(sulfato-κO,O')nickel(II) ethane-1,2-diol solvate.

Zhong KL, Ni C, Wang JM - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The Ni(2+) ion lies on a special position of site symmetry 2.Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure.The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing, Jiangsu Province, People's Republic of China.

ABSTRACT
In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

No MeSH data available.


The molecular structure showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level. The dashed lines represent O—H···O interactions. Unlabeled atoms are related to the labelled atoms by the symmetry operator (-x, y, -z +3/2). Only one disorder component is shown.
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Fap1: The molecular structure showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level. The dashed lines represent O—H···O interactions. Unlabeled atoms are related to the labelled atoms by the symmetry operator (-x, y, -z +3/2). Only one disorder component is shown.


Bis(1,10-phenanthroline-κN,N')(sulfato-κO,O')nickel(II) ethane-1,2-diol solvate.

Zhong KL, Ni C, Wang JM - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level. The dashed lines represent O—H···O interactions. Unlabeled atoms are related to the labelled atoms by the symmetry operator (-x, y, -z +3/2). Only one disorder component is shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977342&req=5

Fap1: The molecular structure showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level. The dashed lines represent O—H···O interactions. Unlabeled atoms are related to the labelled atoms by the symmetry operator (-x, y, -z +3/2). Only one disorder component is shown.
Bottom Line: The Ni(2+) ion lies on a special position of site symmetry 2.Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure.The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing, Jiangsu Province, People's Republic of China.

ABSTRACT
In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

No MeSH data available.