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Dichloridobis{6-methyl-2-[(trimethyl-silyl)amino]pyridine-κN}cobalt(II).

Xue X, Chen X, Tong H - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands.The dihedral angle between the planes of the pyridine rings is 80.06 (5)°.Cohesion within the crystal structure is accomplished by N-H⋯Cl hydrogen bonds.

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ABSTRACT
In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N-H⋯Cl hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
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Fap1: The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.


Dichloridobis{6-methyl-2-[(trimethyl-silyl)amino]pyridine-κN}cobalt(II).

Xue X, Chen X, Tong H - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977306&req=5

Fap1: The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
Bottom Line: In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands.The dihedral angle between the planes of the pyridine rings is 80.06 (5)°.Cohesion within the crystal structure is accomplished by N-H⋯Cl hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N-H⋯Cl hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus