Limits...
Tetra-μ(2)-acetato-bis-{μ(2)-5-meth-oxy-2-[(2-morpholinoeth-yl)iminio-meth-yl]phenolato}tricadmium(II).

Mohd Lair N, Mohd Ali H, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode.The Schiff base anions N,O-chelate to the terminal metal atoms.The morpholine ring assumes a chair conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octa-hedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation.

No MeSH data available.


Related in: MedlinePlus

Thermal ellipsoid plot (Barbour, 2001) of Cd3(C2H3O2)4(C13H19N2O3)2 at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2977297&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of Cd3(C2H3O2)4(C13H19N2O3)2 at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.


Tetra-μ(2)-acetato-bis-{μ(2)-5-meth-oxy-2-[(2-morpholinoeth-yl)iminio-meth-yl]phenolato}tricadmium(II).

Mohd Lair N, Mohd Ali H, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2009)

Thermal ellipsoid plot (Barbour, 2001) of Cd3(C2H3O2)4(C13H19N2O3)2 at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2977297&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of Cd3(C2H3O2)4(C13H19N2O3)2 at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode.The Schiff base anions N,O-chelate to the terminal metal atoms.The morpholine ring assumes a chair conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octa-hedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation.

No MeSH data available.


Related in: MedlinePlus