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[(Di-o-tolyl-phosphino)meth-yl]diphenyl-phosphine sulfide.

Pitroda PP, Badgett AH, Dickey GA, Gray DL, Shelby QD - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, C(27)H(26)P(2)S, the P-C-P angle is 114.33 (13)°.The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons.One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

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ABSTRACT
In the title compound, C(27)H(26)P(2)S, the P-C-P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

No MeSH data available.


Molecular structure of the title compound showing disorder of the phenyl ring C1 to C6 over three sites and the phenyl ring C7 to C12 over two sites with 35% probability ellipsoids for non-H atoms and circles of arbitrary size for H atoms.
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Fap1: Molecular structure of the title compound showing disorder of the phenyl ring C1 to C6 over three sites and the phenyl ring C7 to C12 over two sites with 35% probability ellipsoids for non-H atoms and circles of arbitrary size for H atoms.


[(Di-o-tolyl-phosphino)meth-yl]diphenyl-phosphine sulfide.

Pitroda PP, Badgett AH, Dickey GA, Gray DL, Shelby QD - Acta Crystallogr Sect E Struct Rep Online (2009)

Molecular structure of the title compound showing disorder of the phenyl ring C1 to C6 over three sites and the phenyl ring C7 to C12 over two sites with 35% probability ellipsoids for non-H atoms and circles of arbitrary size for H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970358&req=5

Fap1: Molecular structure of the title compound showing disorder of the phenyl ring C1 to C6 over three sites and the phenyl ring C7 to C12 over two sites with 35% probability ellipsoids for non-H atoms and circles of arbitrary size for H atoms.
Bottom Line: In the title compound, C(27)H(26)P(2)S, the P-C-P angle is 114.33 (13)°.The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons.One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(27)H(26)P(2)S, the P-C-P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

No MeSH data available.