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Bis(acetyl-acetonato-κO,O')-aqua-(diacetyl-methanido-κC)iridium(III).

Chang QW, Xie MJ, Liu WP, Chen XZ, Ye QS - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octa-hedral environment.The complex contains both Ir-O and Ir-C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3).O-H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).

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ABSTRACT
In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octa-hedral environment. The complex contains both Ir-O and Ir-C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3). O-H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).

No MeSH data available.


Packing view, showing the C—H···O hydrogen-bond network between the complexes. Only the H atoms involved in H bonding are drawn. Hydrogen bonds are shown as dashed lines.
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Fap2: Packing view, showing the C—H···O hydrogen-bond network between the complexes. Only the H atoms involved in H bonding are drawn. Hydrogen bonds are shown as dashed lines.


Bis(acetyl-acetonato-κO,O')-aqua-(diacetyl-methanido-κC)iridium(III).

Chang QW, Xie MJ, Liu WP, Chen XZ, Ye QS - Acta Crystallogr Sect E Struct Rep Online (2009)

Packing view, showing the C—H···O hydrogen-bond network between the complexes. Only the H atoms involved in H bonding are drawn. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970352&req=5

Fap2: Packing view, showing the C—H···O hydrogen-bond network between the complexes. Only the H atoms involved in H bonding are drawn. Hydrogen bonds are shown as dashed lines.
Bottom Line: In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octa-hedral environment.The complex contains both Ir-O and Ir-C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3).O-H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octa-hedral environment. The complex contains both Ir-O and Ir-C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3). O-H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).

No MeSH data available.