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catena-Poly[[aqua-(1,10-phenanthroline)cobalt(II)]-μ-4,4'-(propane-1,3-diyldi-oxy)dibenzoato].

Shen SM - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [Co(C(17)H(14)O(6))(C(12)H(8)N(2))(H(2)O)](n), the Co(II) atom is coordinated by a monodentate 4,4'-(propane-1,3-diyldi-oxy)dibenzoate (cpp) dianion, a water mol-ecule and a chelating 1,10-phenanthroline (phen) ligand.A symmetry-generated cpp ligand completes the CoN(2)O(3) trigonal-bipyramidal geometry for the metal ion, with the N atoms occupying both equatorial and axial sites.The bridging cpp ligands form chains propagating in [110] and O-H⋯O hydrogen bonds consolidate the packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Applied Engineering, Zhejiang Economic and Trade Polytechnic, 310018 Hangzhou, People's Republic of China.

ABSTRACT
In the title compound, [Co(C(17)H(14)O(6))(C(12)H(8)N(2))(H(2)O)](n), the Co(II) atom is coordinated by a monodentate 4,4'-(propane-1,3-diyldi-oxy)dibenzoate (cpp) dianion, a water mol-ecule and a chelating 1,10-phenanthroline (phen) ligand. A symmetry-generated cpp ligand completes the CoN(2)O(3) trigonal-bipyramidal geometry for the metal ion, with the N atoms occupying both equatorial and axial sites. The bridging cpp ligands form chains propagating in [110] and O-H⋯O hydrogen bonds consolidate the packing.

No MeSH data available.


Partial packing of (I) showing the formation of a chain along c axis.
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Fap2: Partial packing of (I) showing the formation of a chain along c axis.


catena-Poly[[aqua-(1,10-phenanthroline)cobalt(II)]-μ-4,4'-(propane-1,3-diyldi-oxy)dibenzoato].

Shen SM - Acta Crystallogr Sect E Struct Rep Online (2009)

Partial packing of (I) showing the formation of a chain along c axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970340&req=5

Fap2: Partial packing of (I) showing the formation of a chain along c axis.
Bottom Line: In the title compound, [Co(C(17)H(14)O(6))(C(12)H(8)N(2))(H(2)O)](n), the Co(II) atom is coordinated by a monodentate 4,4'-(propane-1,3-diyldi-oxy)dibenzoate (cpp) dianion, a water mol-ecule and a chelating 1,10-phenanthroline (phen) ligand.A symmetry-generated cpp ligand completes the CoN(2)O(3) trigonal-bipyramidal geometry for the metal ion, with the N atoms occupying both equatorial and axial sites.The bridging cpp ligands form chains propagating in [110] and O-H⋯O hydrogen bonds consolidate the packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Applied Engineering, Zhejiang Economic and Trade Polytechnic, 310018 Hangzhou, People's Republic of China.

ABSTRACT
In the title compound, [Co(C(17)H(14)O(6))(C(12)H(8)N(2))(H(2)O)](n), the Co(II) atom is coordinated by a monodentate 4,4'-(propane-1,3-diyldi-oxy)dibenzoate (cpp) dianion, a water mol-ecule and a chelating 1,10-phenanthroline (phen) ligand. A symmetry-generated cpp ligand completes the CoN(2)O(3) trigonal-bipyramidal geometry for the metal ion, with the N atoms occupying both equatorial and axial sites. The bridging cpp ligands form chains propagating in [110] and O-H⋯O hydrogen bonds consolidate the packing.

No MeSH data available.