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Bis[4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-)-κO,O]bis-(1,10-phenanthroline-κN,N')dysprosium(III) dihydrate.

Liu X, Xing H, Miao J, Jia M, Chen Z - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti-prismatic geometry by two chelating 1,10-phenanthroline mol-ecules as well as two 4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-) anions.N-H⋯O and O-H⋯O hydrogen bonds help to stabilize the crystal structure.The H atom involved in an N-H⋯N hydrogen bond is disordered around a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Guangxi Normal University, Yucai Road 15, Guilin 541004, People's Republic of China.

ABSTRACT
In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti-prismatic geometry by two chelating 1,10-phenanthroline mol-ecules as well as two 4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-) anions. N-H⋯O and O-H⋯O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N-H⋯N hydrogen bond is disordered around a twofold rotation axis.

No MeSH data available.


The molecular structure of the title compound with the atom-numbering scheme and 30% displacement ellipsoids.
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Fap1: The molecular structure of the title compound with the atom-numbering scheme and 30% displacement ellipsoids.


Bis[4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-)-κO,O]bis-(1,10-phenanthroline-κN,N')dysprosium(III) dihydrate.

Liu X, Xing H, Miao J, Jia M, Chen Z - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title compound with the atom-numbering scheme and 30% displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970315&req=5

Fap1: The molecular structure of the title compound with the atom-numbering scheme and 30% displacement ellipsoids.
Bottom Line: In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti-prismatic geometry by two chelating 1,10-phenanthroline mol-ecules as well as two 4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-) anions.N-H⋯O and O-H⋯O hydrogen bonds help to stabilize the crystal structure.The H atom involved in an N-H⋯N hydrogen bond is disordered around a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Guangxi Normal University, Yucai Road 15, Guilin 541004, People's Republic of China.

ABSTRACT
In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti-prismatic geometry by two chelating 1,10-phenanthroline mol-ecules as well as two 4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-) anions. N-H⋯O and O-H⋯O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N-H⋯N hydrogen bond is disordered around a twofold rotation axis.

No MeSH data available.