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2-(Dimethyl-amino-meth-yl)phenyl phenyl telluride.

Chakraborty T, Singh HB, Butcher RJ - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter-action between the amino N and Te(II) atoms.The Te-C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) Å] due to the hypervalent inter-action.The bond angle for the trans N-Te-C atoms [164.92 (6)°] deviates significantly from linearity.

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ABSTRACT
The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter-action between the amino N and Te(II) atoms. The Te-C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) Å] due to the hypervalent inter-action. The bond angle for the trans N-Te-C atoms [164.92 (6)°] deviates significantly from linearity.

No MeSH data available.


The molecular structure of C15H17NTe the showing the atom numbering scheme and 50% probability displacement ellipsoids. The secondary interaction between the N and Te is shown as a dashed line.
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Fap1: The molecular structure of C15H17NTe the showing the atom numbering scheme and 50% probability displacement ellipsoids. The secondary interaction between the N and Te is shown as a dashed line.


2-(Dimethyl-amino-meth-yl)phenyl phenyl telluride.

Chakraborty T, Singh HB, Butcher RJ - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of C15H17NTe the showing the atom numbering scheme and 50% probability displacement ellipsoids. The secondary interaction between the N and Te is shown as a dashed line.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970312&req=5

Fap1: The molecular structure of C15H17NTe the showing the atom numbering scheme and 50% probability displacement ellipsoids. The secondary interaction between the N and Te is shown as a dashed line.
Bottom Line: The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter-action between the amino N and Te(II) atoms.The Te-C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) Å] due to the hypervalent inter-action.The bond angle for the trans N-Te-C atoms [164.92 (6)°] deviates significantly from linearity.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter-action between the amino N and Te(II) atoms. The Te-C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) Å] due to the hypervalent inter-action. The bond angle for the trans N-Te-C atoms [164.92 (6)°] deviates significantly from linearity.

No MeSH data available.