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(Benzyl-amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate.

Ravichandran K, Ramesh P, Tamilselvan M, Anbalagan K, Ponnuswamy MN - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol-ecule in the asymmetric unit.Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion.The crystal packing is through N-H⋯O, N-H⋯Cl and O-H⋯Cl inter-actions.

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ABSTRACT
In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol-ecule in the asymmetric unit. Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion. The crystal packing is through N-H⋯O, N-H⋯Cl and O-H⋯Cl inter-actions.

No MeSH data available.


The crystal packing of the molecules viewed down the b–axis. H atoms not involved in hydrogen bonding have been omitted for clarity.
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Fap2: The crystal packing of the molecules viewed down the b–axis. H atoms not involved in hydrogen bonding have been omitted for clarity.


(Benzyl-amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate.

Ravichandran K, Ramesh P, Tamilselvan M, Anbalagan K, Ponnuswamy MN - Acta Crystallogr Sect E Struct Rep Online (2009)

The crystal packing of the molecules viewed down the b–axis. H atoms not involved in hydrogen bonding have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970310&req=5

Fap2: The crystal packing of the molecules viewed down the b–axis. H atoms not involved in hydrogen bonding have been omitted for clarity.
Bottom Line: In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol-ecule in the asymmetric unit.Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion.The crystal packing is through N-H⋯O, N-H⋯Cl and O-H⋯Cl inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol-ecule in the asymmetric unit. Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion. The crystal packing is through N-H⋯O, N-H⋯Cl and O-H⋯Cl inter-actions.

No MeSH data available.