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catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth-yl)methyl-ene]glycinato].

Xue LW, Li XW, Zhao GQ, Peng QL - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position.The apical Cu-O bond [2.3520 (16) Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139 (14)-2.0136 (17) Å].The carboxyl-ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu-O bond [2.3520 (16) Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139 (14)-2.0136 (17) Å]. The carboxyl-ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis.

No MeSH data available.


A view of the crystal packing along the c axis.
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Fap2: A view of the crystal packing along the c axis.


catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth-yl)methyl-ene]glycinato].

Xue LW, Li XW, Zhao GQ, Peng QL - Acta Crystallogr Sect E Struct Rep Online (2009)

A view of the crystal packing along the c axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970287&req=5

Fap2: A view of the crystal packing along the c axis.
Bottom Line: In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position.The apical Cu-O bond [2.3520 (16) Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139 (14)-2.0136 (17) Å].The carboxyl-ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu-O bond [2.3520 (16) Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139 (14)-2.0136 (17) Å]. The carboxyl-ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis.

No MeSH data available.