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Poly[[aqua-(μ-4,4'-bipyridyl-κN:N')bis-(μ-formato-κO:O')iron(II)] tetra-hydrate].

Jiang B, Liu Z - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, {[Fe(CHO(2))(2)(C(10)H(8)N(2))(H(2)O)]·4H(2)O}(n), the Fe(II) ion is coordinated by two 4,4'-bipyridyl (4,4'-bpy) ligands, three formate ligands and one water molecule.The three-dimensional structure is stabilized by extensive O-H⋯O hydrogen bonding.The crystals were twinned containing a 0.84:0.16 racemate.

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ABSTRACT
In the title compound, {[Fe(CHO(2))(2)(C(10)H(8)N(2))(H(2)O)]·4H(2)O}(n), the Fe(II) ion is coordinated by two 4,4'-bipyridyl (4,4'-bpy) ligands, three formate ligands and one water molecule. The slightly distorted octahedral FeN(2)O(4) coordination results from the N atoms of two bridging 4,4'-bpy ligands, the O atoms of two bridging HCOO(-) anions of anti-anti mode, all in trans positions around the metal centre, and the O atoms of one terminal HCOO(-) anion and of one water molecule. The bridging formate ligands link the metal ions into chains that are further connected via 4,4'-bpy ligands into a framework structure. The three-dimensional structure is stabilized by extensive O-H⋯O hydrogen bonding. The crystals were twinned containing a 0.84:0.16 racemate.

No MeSH data available.


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Packing diagram of the title compound showing hydrogen bonding; H-atoms not involved in H-bonds have been excluded for clarity.
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Fap2: Packing diagram of the title compound showing hydrogen bonding; H-atoms not involved in H-bonds have been excluded for clarity.


Poly[[aqua-(μ-4,4'-bipyridyl-κN:N')bis-(μ-formato-κO:O')iron(II)] tetra-hydrate].

Jiang B, Liu Z - Acta Crystallogr Sect E Struct Rep Online (2009)

Packing diagram of the title compound showing hydrogen bonding; H-atoms not involved in H-bonds have been excluded for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970270&req=5

Fap2: Packing diagram of the title compound showing hydrogen bonding; H-atoms not involved in H-bonds have been excluded for clarity.
Bottom Line: In the title compound, {[Fe(CHO(2))(2)(C(10)H(8)N(2))(H(2)O)]·4H(2)O}(n), the Fe(II) ion is coordinated by two 4,4'-bipyridyl (4,4'-bpy) ligands, three formate ligands and one water molecule.The three-dimensional structure is stabilized by extensive O-H⋯O hydrogen bonding.The crystals were twinned containing a 0.84:0.16 racemate.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, {[Fe(CHO(2))(2)(C(10)H(8)N(2))(H(2)O)]·4H(2)O}(n), the Fe(II) ion is coordinated by two 4,4'-bipyridyl (4,4'-bpy) ligands, three formate ligands and one water molecule. The slightly distorted octahedral FeN(2)O(4) coordination results from the N atoms of two bridging 4,4'-bpy ligands, the O atoms of two bridging HCOO(-) anions of anti-anti mode, all in trans positions around the metal centre, and the O atoms of one terminal HCOO(-) anion and of one water molecule. The bridging formate ligands link the metal ions into chains that are further connected via 4,4'-bpy ligands into a framework structure. The three-dimensional structure is stabilized by extensive O-H⋯O hydrogen bonding. The crystals were twinned containing a 0.84:0.16 racemate.

No MeSH data available.


Related in: MedlinePlus