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Bis[5-(2-amino-3-pyrid-yl)tetra-zolato]copper(II).

Guo M - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid-yl)tetra-zolate ligands in a slightly distorted square-planar environment.There are weak intra-molecular N-H⋯N hydrogen bonds between the two ligands.In the crystal structure, there are significant π-π stacking inter-actions between symmetry-related tetra-zole and pyridine rings, with a centroid-centroid distance of 3.6025 (18)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid-yl)tetra-zolate ligands in a slightly distorted square-planar environment. There are weak intra-molecular N-H⋯N hydrogen bonds between the two ligands. In the crystal structure, there are significant π-π stacking inter-actions between symmetry-related tetra-zole and pyridine rings, with a centroid-centroid distance of 3.6025 (18)°.

No MeSH data available.


The molecular structure of the title compound with the atomic numbering scheme. Displacement ellipsoids were drawn at the 30% probability level. Symmetry code: (a) -x+1, -y+1, -z+1. Hydrogen bonds are shown as dashed lines.
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Fap1: The molecular structure of the title compound with the atomic numbering scheme. Displacement ellipsoids were drawn at the 30% probability level. Symmetry code: (a) -x+1, -y+1, -z+1. Hydrogen bonds are shown as dashed lines.


Bis[5-(2-amino-3-pyrid-yl)tetra-zolato]copper(II).

Guo M - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title compound with the atomic numbering scheme. Displacement ellipsoids were drawn at the 30% probability level. Symmetry code: (a) -x+1, -y+1, -z+1. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970265&req=5

Fap1: The molecular structure of the title compound with the atomic numbering scheme. Displacement ellipsoids were drawn at the 30% probability level. Symmetry code: (a) -x+1, -y+1, -z+1. Hydrogen bonds are shown as dashed lines.
Bottom Line: In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid-yl)tetra-zolate ligands in a slightly distorted square-planar environment.There are weak intra-molecular N-H⋯N hydrogen bonds between the two ligands.In the crystal structure, there are significant π-π stacking inter-actions between symmetry-related tetra-zole and pyridine rings, with a centroid-centroid distance of 3.6025 (18)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid-yl)tetra-zolate ligands in a slightly distorted square-planar environment. There are weak intra-molecular N-H⋯N hydrogen bonds between the two ligands. In the crystal structure, there are significant π-π stacking inter-actions between symmetry-related tetra-zole and pyridine rings, with a centroid-centroid distance of 3.6025 (18)°.

No MeSH data available.