Limits...
4-(2-Methyl-piperidin-1-ylcarbon-yl)pyridinium hexachloridoantimonate(V).

Wang B - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively.The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation.The crystal packing is stabilized by N-H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the hexa-chlorido-animonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octa-hedral coordination. In the 4-(2-methyl-piperidine-1-carbon-yl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N-H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010].

No MeSH data available.


A view of the crystal packing of the title compound, Dashed lines indicate N–H···O hydrogen bonds which form infinite, one-dimensional chains along the (011) plane of the unit cell.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2970264&req=5

Fap2: A view of the crystal packing of the title compound, Dashed lines indicate N–H···O hydrogen bonds which form infinite, one-dimensional chains along the (011) plane of the unit cell.


4-(2-Methyl-piperidin-1-ylcarbon-yl)pyridinium hexachloridoantimonate(V).

Wang B - Acta Crystallogr Sect E Struct Rep Online (2009)

A view of the crystal packing of the title compound, Dashed lines indicate N–H···O hydrogen bonds which form infinite, one-dimensional chains along the (011) plane of the unit cell.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970264&req=5

Fap2: A view of the crystal packing of the title compound, Dashed lines indicate N–H···O hydrogen bonds which form infinite, one-dimensional chains along the (011) plane of the unit cell.
Bottom Line: The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively.The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation.The crystal packing is stabilized by N-H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the hexa-chlorido-animonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octa-hedral coordination. In the 4-(2-methyl-piperidine-1-carbon-yl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N-H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010].

No MeSH data available.