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(R,R)-(N,N'-Diferrocenylcyclo-hexane-1,2-diyldiimino)dibenzonitrile.

Chen F - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The cyclo-penta-dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives.The dihedral angle formed by the two benzene rings is 20.2 (3)°.In the crystal, mol-ecules are linked by C-H⋯N inter-actions, forming an infinite two-dimensional network.

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Affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclo-hexane-1,2-diamine unit. The cyclo-penta-dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives. The dihedral angle formed by the two benzene rings is 20.2 (3)°. The Fe-C bond lengths to the two substituted Cp rings vary from 2.014 (4) to 2.070 (3) Å, and are in the normal range. In the crystal, mol-ecules are linked by C-H⋯N inter-actions, forming an infinite two-dimensional network.

No MeSH data available.


A view of the molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level [H-atoms have been omitted for clarity].
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Fap1: A view of the molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level [H-atoms have been omitted for clarity].


(R,R)-(N,N'-Diferrocenylcyclo-hexane-1,2-diyldiimino)dibenzonitrile.

Chen F - Acta Crystallogr Sect E Struct Rep Online (2009)

A view of the molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level [H-atoms have been omitted for clarity].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970254&req=5

Fap1: A view of the molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level [H-atoms have been omitted for clarity].
Bottom Line: The cyclo-penta-dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives.The dihedral angle formed by the two benzene rings is 20.2 (3)°.In the crystal, mol-ecules are linked by C-H⋯N inter-actions, forming an infinite two-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclo-hexane-1,2-diamine unit. The cyclo-penta-dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives. The dihedral angle formed by the two benzene rings is 20.2 (3)°. The Fe-C bond lengths to the two substituted Cp rings vary from 2.014 (4) to 2.070 (3) Å, and are in the normal range. In the crystal, mol-ecules are linked by C-H⋯N inter-actions, forming an infinite two-dimensional network.

No MeSH data available.