Limits...
Bis(2,2'-bipyridine)(5-isothio-cyanato-1,10-phenanthroline)ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile solvate.

Nag S, Pal AK, Hanan GS - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate).The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand.The isothio-cyanate group is almost linear, with an N-C-S angle of 174.4 (6)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Département de Chimie, Université de Montréal, CP 6128, Succ. Centre-ville, Montréal, Québec, Canada H3C 3J7.

ABSTRACT
The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio-cyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexa-fluoridophosphate counter-anions are located on inversion centres.

No MeSH data available.


Related in: MedlinePlus

View of the cation in the title compound. Thermal ellipsoids are shown at the 50% probability level. H atoms, hexafluoridophosphate anions and the acetonitrile solvent molecule have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2970250&req=5

Fap1: View of the cation in the title compound. Thermal ellipsoids are shown at the 50% probability level. H atoms, hexafluoridophosphate anions and the acetonitrile solvent molecule have been omitted for clarity.


Bis(2,2'-bipyridine)(5-isothio-cyanato-1,10-phenanthroline)ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile solvate.

Nag S, Pal AK, Hanan GS - Acta Crystallogr Sect E Struct Rep Online (2009)

View of the cation in the title compound. Thermal ellipsoids are shown at the 50% probability level. H atoms, hexafluoridophosphate anions and the acetonitrile solvent molecule have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970250&req=5

Fap1: View of the cation in the title compound. Thermal ellipsoids are shown at the 50% probability level. H atoms, hexafluoridophosphate anions and the acetonitrile solvent molecule have been omitted for clarity.
Bottom Line: The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate).The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand.The isothio-cyanate group is almost linear, with an N-C-S angle of 174.4 (6)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Département de Chimie, Université de Montréal, CP 6128, Succ. Centre-ville, Montréal, Québec, Canada H3C 3J7.

ABSTRACT
The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio-cyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexa-fluoridophosphate counter-anions are located on inversion centres.

No MeSH data available.


Related in: MedlinePlus