Limits...
Aqua-tris(1H-benzimidazole-κN)(dichloro-acetato-κO)copper(II) dichloro-acetate dihydrate.

Li YF, Jian FF - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The compound shows a regular trigonal-bipyramidal stereochemistry.The mol-ecular structure and packing are stabilized by O-H⋯O and N-H⋯O hydrogen bonds.The Cl atoms are disordered over two sites, with relative occupancies 0.67 (3) and 0.33 (3).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Cu(C(2)HCl(2)O(2))(C(7)H(6)N(2))(3)(H(2)O)]C(2)HCl(2)O(2)·2H(2)O, was prepared by reaction of copper(II) 2,2-dichloro-acetic acid and benzimidazole in ethanol solution. The compound shows a regular trigonal-bipyramidal stereochemistry. The Cu(II) centre possesses a five-coordinated environment, coordinated by three N atoms from the three benzimidazole ligands and two O atoms, one from the dichloro-acetate ligand and the other from the coordinated water mol-ecule. The mol-ecular structure and packing are stabilized by O-H⋯O and N-H⋯O hydrogen bonds. The Cl atoms are disordered over two sites, with relative occupancies 0.67 (3) and 0.33 (3).

No MeSH data available.


The molecular structure and atom-labeling scheme for (I), with displacement ellipsoids drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2970244&req=5

Fap1: The molecular structure and atom-labeling scheme for (I), with displacement ellipsoids drawn at the 30% probability level.


Aqua-tris(1H-benzimidazole-κN)(dichloro-acetato-κO)copper(II) dichloro-acetate dihydrate.

Li YF, Jian FF - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure and atom-labeling scheme for (I), with displacement ellipsoids drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970244&req=5

Fap1: The molecular structure and atom-labeling scheme for (I), with displacement ellipsoids drawn at the 30% probability level.
Bottom Line: The compound shows a regular trigonal-bipyramidal stereochemistry.The mol-ecular structure and packing are stabilized by O-H⋯O and N-H⋯O hydrogen bonds.The Cl atoms are disordered over two sites, with relative occupancies 0.67 (3) and 0.33 (3).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Cu(C(2)HCl(2)O(2))(C(7)H(6)N(2))(3)(H(2)O)]C(2)HCl(2)O(2)·2H(2)O, was prepared by reaction of copper(II) 2,2-dichloro-acetic acid and benzimidazole in ethanol solution. The compound shows a regular trigonal-bipyramidal stereochemistry. The Cu(II) centre possesses a five-coordinated environment, coordinated by three N atoms from the three benzimidazole ligands and two O atoms, one from the dichloro-acetate ligand and the other from the coordinated water mol-ecule. The mol-ecular structure and packing are stabilized by O-H⋯O and N-H⋯O hydrogen bonds. The Cl atoms are disordered over two sites, with relative occupancies 0.67 (3) and 0.33 (3).

No MeSH data available.