Limits...
N-Cyano-7α-methoxy-carbonyl-6,14-endo-ethenotetra-hydro-northebaine.

Odabaşoğlu M, Yavuz S, Pamir O, Büyükgüngör O, Yıldırır Y - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The benzene-fused cyclo-hexene ring adopts an envelope conformation.An intra-molecular C-H⋯O hydrogen bond is observed.Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT

In the title compound (systematic name: methyl 17-cyano-3,6-dimeth-oxy-4,5α-ep-oxy-6,14-endo-ethenomorphinan-7-carboxyl-ate), C(23)H(24)N(2)O(5), the dihydro-furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo-hexene ring adopts an envelope conformation. An intra-molecular C-H⋯O hydrogen bond is observed. Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.

No MeSH data available.


Preparation of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2970118&req=5

Fap4: Preparation of the title compound.


N-Cyano-7α-methoxy-carbonyl-6,14-endo-ethenotetra-hydro-northebaine.

Odabaşoğlu M, Yavuz S, Pamir O, Büyükgüngör O, Yıldırır Y - Acta Crystallogr Sect E Struct Rep Online (2009)

Preparation of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970118&req=5

Fap4: Preparation of the title compound.
Bottom Line: The benzene-fused cyclo-hexene ring adopts an envelope conformation.An intra-molecular C-H⋯O hydrogen bond is observed.Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT

In the title compound (systematic name: methyl 17-cyano-3,6-dimeth-oxy-4,5α-ep-oxy-6,14-endo-ethenomorphinan-7-carboxyl-ate), C(23)H(24)N(2)O(5), the dihydro-furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo-hexene ring adopts an envelope conformation. An intra-molecular C-H⋯O hydrogen bond is observed. Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.

No MeSH data available.