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Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.

Cai YJ, Li J, Huang P, Zeng QF - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion.In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds.

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Affiliation: Engineering Research Center for Clean Production of Textile Dyeing and Printing, Ministry of Education, Wuhan 430073, People's Republic of China.

ABSTRACT
In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds.

No MeSH data available.


The molecular structure of (I) showing 30% probability displacement ellipsoids. Atoms with the suffix A are generated by the symmetry operation (1–x, y, 3/2–z).
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Fap1: The molecular structure of (I) showing 30% probability displacement ellipsoids. Atoms with the suffix A are generated by the symmetry operation (1–x, y, 3/2–z).


Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.

Cai YJ, Li J, Huang P, Zeng QF - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of (I) showing 30% probability displacement ellipsoids. Atoms with the suffix A are generated by the symmetry operation (1–x, y, 3/2–z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2970116&req=5

Fap1: The molecular structure of (I) showing 30% probability displacement ellipsoids. Atoms with the suffix A are generated by the symmetry operation (1–x, y, 3/2–z).
Bottom Line: In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion.In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Engineering Research Center for Clean Production of Textile Dyeing and Printing, Ministry of Education, Wuhan 430073, People's Republic of China.

ABSTRACT
In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds.

No MeSH data available.