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Bis(thio-cyanato-κN)[tris-(2-pyridylmeth-yl)amine-κN,N',N'',N''']nickel(II) methanol hemisolvate.

Randeniya SR, Norman RE - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms.The distances and angles are typical for Ni(II)-TPA complexes.The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Box 2117, Sam Houston State University, Huntsville, TX 77341, USA.

ABSTRACT
The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

No MeSH data available.


Related in: MedlinePlus

Perspective drawing of the asymmetric unit with displacement ellipsoids drawn at the 50% probability level and hydrogen atoms removed.
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Fap1: Perspective drawing of the asymmetric unit with displacement ellipsoids drawn at the 50% probability level and hydrogen atoms removed.


Bis(thio-cyanato-κN)[tris-(2-pyridylmeth-yl)amine-κN,N',N'',N''']nickel(II) methanol hemisolvate.

Randeniya SR, Norman RE - Acta Crystallogr Sect E Struct Rep Online (2009)

Perspective drawing of the asymmetric unit with displacement ellipsoids drawn at the 50% probability level and hydrogen atoms removed.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969451&req=5

Fap1: Perspective drawing of the asymmetric unit with displacement ellipsoids drawn at the 50% probability level and hydrogen atoms removed.
Bottom Line: The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms.The distances and angles are typical for Ni(II)-TPA complexes.The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Box 2117, Sam Houston State University, Huntsville, TX 77341, USA.

ABSTRACT
The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

No MeSH data available.


Related in: MedlinePlus