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[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide.

Harding DJ, Harding P, Adams H - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion.In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

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ABSTRACT
In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion. In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

No MeSH data available.


Related in: MedlinePlus

The molecular packing in (I) showing the three C—H···π interactions. Only selected atoms are labelled or shown for clairty [Symmetry codes:(i) 4/3 - x + y, 2/3 - x, -1/3 + z; (ii) 4/3 - y, -1/3 + x-y, -1/3 + z].
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Fap2: The molecular packing in (I) showing the three C—H···π interactions. Only selected atoms are labelled or shown for clairty [Symmetry codes:(i) 4/3 - x + y, 2/3 - x, -1/3 + z; (ii) 4/3 - y, -1/3 + x-y, -1/3 + z].


[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide.

Harding DJ, Harding P, Adams H - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular packing in (I) showing the three C—H···π interactions. Only selected atoms are labelled or shown for clairty [Symmetry codes:(i) 4/3 - x + y, 2/3 - x, -1/3 + z; (ii) 4/3 - y, -1/3 + x-y, -1/3 + z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969450&req=5

Fap2: The molecular packing in (I) showing the three C—H···π interactions. Only selected atoms are labelled or shown for clairty [Symmetry codes:(i) 4/3 - x + y, 2/3 - x, -1/3 + z; (ii) 4/3 - y, -1/3 + x-y, -1/3 + z].
Bottom Line: In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion.In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion. In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

No MeSH data available.


Related in: MedlinePlus