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[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide.

Harding DJ, Harding P, Adams H - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion.In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

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ABSTRACT
In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion. In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level. [Symmetry codes:(i) -x + y+1, -x + 1, z; (ii) -y + 1, x-y, z].
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Fap1: The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level. [Symmetry codes:(i) -x + y+1, -x + 1, z; (ii) -y + 1, x-y, z].


[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide.

Harding DJ, Harding P, Adams H - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level. [Symmetry codes:(i) -x + y+1, -x + 1, z; (ii) -y + 1, x-y, z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969450&req=5

Fap1: The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level. [Symmetry codes:(i) -x + y+1, -x + 1, z; (ii) -y + 1, x-y, z].
Bottom Line: In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion.In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion. In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.

No MeSH data available.


Related in: MedlinePlus