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Bis[(1S*,2S*)-trans-1,2-bis-(diphenyl-phosphin-oxy)cyclo-hexa-ne]chlorido-ruthenium(II) trifluoro-methane-sulfonate dichloro-methane disolvate.

Clark GR, Lensink C, Slade AT, Wright LJ - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The crystal structure of a racemic mixture of the title ruthenium(II) complex, [RuCl(C(30)H(30)O(2)P(2))(2)]CF(3)SO(3)·2CH(2)Cl(2), reveals that the coordination geometry about the coordinatively unsaturated metal centre is approximately trigonal-pyramidal, with the chlorine atom occupying one of the equatorial positions.The axial Ru-P bonds are longer than the equatorial Ru-P bonds and there is an acute P-Ru-P angle.

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ABSTRACT
The crystal structure of a racemic mixture of the title ruthenium(II) complex, [RuCl(C(30)H(30)O(2)P(2))(2)]CF(3)SO(3)·2CH(2)Cl(2), reveals that the coordination geometry about the coordinatively unsaturated metal centre is approximately trigonal-pyramidal, with the chlorine atom occupying one of the equatorial positions. The axial Ru-P bonds are longer than the equatorial Ru-P bonds and there is an acute P-Ru-P angle.

No MeSH data available.


Reaction scheme.
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Fap1: Reaction scheme.


Bis[(1S*,2S*)-trans-1,2-bis-(diphenyl-phosphin-oxy)cyclo-hexa-ne]chlorido-ruthenium(II) trifluoro-methane-sulfonate dichloro-methane disolvate.

Clark GR, Lensink C, Slade AT, Wright LJ - Acta Crystallogr Sect E Struct Rep Online (2009)

Reaction scheme.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969446&req=5

Fap1: Reaction scheme.
Bottom Line: The crystal structure of a racemic mixture of the title ruthenium(II) complex, [RuCl(C(30)H(30)O(2)P(2))(2)]CF(3)SO(3)·2CH(2)Cl(2), reveals that the coordination geometry about the coordinatively unsaturated metal centre is approximately trigonal-pyramidal, with the chlorine atom occupying one of the equatorial positions.The axial Ru-P bonds are longer than the equatorial Ru-P bonds and there is an acute P-Ru-P angle.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The crystal structure of a racemic mixture of the title ruthenium(II) complex, [RuCl(C(30)H(30)O(2)P(2))(2)]CF(3)SO(3)·2CH(2)Cl(2), reveals that the coordination geometry about the coordinatively unsaturated metal centre is approximately trigonal-pyramidal, with the chlorine atom occupying one of the equatorial positions. The axial Ru-P bonds are longer than the equatorial Ru-P bonds and there is an acute P-Ru-P angle.

No MeSH data available.