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(μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate.

Lu XP, Zhu ML, Lu LP - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion.In the crystal, inter-molecular O-H⋯O hydrogen bonds link the component units into a three-dimensional network.Two short C-H⋯O contacts are also seen.

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ABSTRACT
In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the component units into a three-dimensional network. Two short C-H⋯O contacts are also seen.

No MeSH data available.


The structure of (I) with displacement ellipsoids drawn at the 30% probability level for Non-H atoms.
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Fap1: The structure of (I) with displacement ellipsoids drawn at the 30% probability level for Non-H atoms.


(μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate.

Lu XP, Zhu ML, Lu LP - Acta Crystallogr Sect E Struct Rep Online (2009)

The structure of (I) with displacement ellipsoids drawn at the 30% probability level for Non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969424&req=5

Fap1: The structure of (I) with displacement ellipsoids drawn at the 30% probability level for Non-H atoms.
Bottom Line: In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion.In the crystal, inter-molecular O-H⋯O hydrogen bonds link the component units into a three-dimensional network.Two short C-H⋯O contacts are also seen.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the component units into a three-dimensional network. Two short C-H⋯O contacts are also seen.

No MeSH data available.