Limits...
2,3-Diamino-pyridinium benzoate.

Balasubramani K, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The carboxyl-ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°.In the crystal structure, N-H⋯O hydrogen bonds between 2,3-diamino-pyridinium cations and benzoate anions, and π-π inter-actions between the pyridinium rings [centroid-centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001).In the network, N-H⋯O hydrogen bonds form R(2) (2)(8) and R(2) (1)(7) ring motifs.

View Article: PubMed Central - HTML - PubMed

Affiliation: X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

ABSTRACT
In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (-), the pyridine N atom is protonated. The carboxyl-ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N-H⋯O hydrogen bonds between 2,3-diamino-pyridinium cations and benzoate anions, and π-π inter-actions between the pyridinium rings [centroid-centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001). In the network, N-H⋯O hydrogen bonds form R(2) (2)(8) and R(2) (1)(7) ring motifs.

No MeSH data available.


Part of the crystal packing of the title compound. Dashed lines indicate hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2969407&req=5

Fap2: Part of the crystal packing of the title compound. Dashed lines indicate hydrogen bonds.


2,3-Diamino-pyridinium benzoate.

Balasubramani K, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2009)

Part of the crystal packing of the title compound. Dashed lines indicate hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969407&req=5

Fap2: Part of the crystal packing of the title compound. Dashed lines indicate hydrogen bonds.
Bottom Line: The carboxyl-ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°.In the crystal structure, N-H⋯O hydrogen bonds between 2,3-diamino-pyridinium cations and benzoate anions, and π-π inter-actions between the pyridinium rings [centroid-centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001).In the network, N-H⋯O hydrogen bonds form R(2) (2)(8) and R(2) (1)(7) ring motifs.

View Article: PubMed Central - HTML - PubMed

Affiliation: X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

ABSTRACT
In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (-), the pyridine N atom is protonated. The carboxyl-ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N-H⋯O hydrogen bonds between 2,3-diamino-pyridinium cations and benzoate anions, and π-π inter-actions between the pyridinium rings [centroid-centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001). In the network, N-H⋯O hydrogen bonds form R(2) (2)(8) and R(2) (1)(7) ring motifs.

No MeSH data available.