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Bis(3,5-dimethyl-pyridine-κN)bis-(tri-tert-butoxy-silanethiol-ato-κS)chromium(II) toluene solvate.

Ciborska A, Baranowska K, Wojnowski W - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title chromium silanethiol-ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement.The mononuclear mol-ecule lies on a twofold axis that passes through the pyridine N atoms.The toluene solvent mol-ecule is equally disordered about a twofold axis.

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Affiliation: Department of Chemistry, Technical University of Gdańsk, 11/12 G. Narutowicz St., 80233-PL Gdańsk, Poland.

ABSTRACT
In the title chromium silanethiol-ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol-ecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent mol-ecule is equally disordered about a twofold axis.

No MeSH data available.


A view of the molecule of (I), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level and H atoms have been omitted.
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Fap1: A view of the molecule of (I), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level and H atoms have been omitted.


Bis(3,5-dimethyl-pyridine-κN)bis-(tri-tert-butoxy-silanethiol-ato-κS)chromium(II) toluene solvate.

Ciborska A, Baranowska K, Wojnowski W - Acta Crystallogr Sect E Struct Rep Online (2009)

A view of the molecule of (I), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level and H atoms have been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969383&req=5

Fap1: A view of the molecule of (I), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level and H atoms have been omitted.
Bottom Line: In the title chromium silanethiol-ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement.The mononuclear mol-ecule lies on a twofold axis that passes through the pyridine N atoms.The toluene solvent mol-ecule is equally disordered about a twofold axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Technical University of Gdańsk, 11/12 G. Narutowicz St., 80233-PL Gdańsk, Poland.

ABSTRACT
In the title chromium silanethiol-ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol-ecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent mol-ecule is equally disordered about a twofold axis.

No MeSH data available.