Limits...
A one-dimensional cadmium(II) complex supported by a sulfur-nitro-gen mixed-donor ligand.

Gao Q, Zhang CY, Cui Y, Xie YB - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, catena-poly[cadmium(II)-bis-(μ-5-am-ino-1,3,4-thia-diazole-2-thiol-ato)-κ(2)N(3):S(2);κ(2)S(2):N(3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thia-diazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetra-hedral geometry.The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N-H⋯N and N-H⋯S hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, People's Republic of China.

ABSTRACT
In the title compound, catena-poly[cadmium(II)-bis-(μ-5-am-ino-1,3,4-thia-diazole-2-thiol-ato)-κ(2)N(3):S(2);κ(2)S(2):N(3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thia-diazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetra-hedral geometry. The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N-H⋯N and N-H⋯S hydrogen bonds into a three-dimensional network.

No MeSH data available.


The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level for non-hydrogen atoms. Symmetry related atoms have the following symmetry codes: A = x, -y + 1, z + 1/2 B = -x + 1, -y + 1, -z AA= -x + 1, y, -z+1/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2969370&req=5

Fap1: The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level for non-hydrogen atoms. Symmetry related atoms have the following symmetry codes: A = x, -y + 1, z + 1/2 B = -x + 1, -y + 1, -z AA= -x + 1, y, -z+1/2.


A one-dimensional cadmium(II) complex supported by a sulfur-nitro-gen mixed-donor ligand.

Gao Q, Zhang CY, Cui Y, Xie YB - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level for non-hydrogen atoms. Symmetry related atoms have the following symmetry codes: A = x, -y + 1, z + 1/2 B = -x + 1, -y + 1, -z AA= -x + 1, y, -z+1/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969370&req=5

Fap1: The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level for non-hydrogen atoms. Symmetry related atoms have the following symmetry codes: A = x, -y + 1, z + 1/2 B = -x + 1, -y + 1, -z AA= -x + 1, y, -z+1/2.
Bottom Line: In the title compound, catena-poly[cadmium(II)-bis-(μ-5-am-ino-1,3,4-thia-diazole-2-thiol-ato)-κ(2)N(3):S(2);κ(2)S(2):N(3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thia-diazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetra-hedral geometry.The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N-H⋯N and N-H⋯S hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, People's Republic of China.

ABSTRACT
In the title compound, catena-poly[cadmium(II)-bis-(μ-5-am-ino-1,3,4-thia-diazole-2-thiol-ato)-κ(2)N(3):S(2);κ(2)S(2):N(3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thia-diazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetra-hedral geometry. The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N-H⋯N and N-H⋯S hydrogen bonds into a three-dimensional network.

No MeSH data available.